Coordination Chemistry Dictates the Structural Defects in Lead Halide Perovskites. Issue 18 (12th July 2016)

• Record Type: Journal Article
• Authors: Rahimnejad, Sara; Kovalenko, Alexander; Forés, Sergio Martí; Aranda, Clara; Guerrero, Antonio
• Is Part Of: Chemphyschem. Volume 17:Issue 18(2016)
• Page Start: 2795
• Page End: 2798
• Publication Date: 2016-07-12
• Subjects: absorption -- coordination chemistry -- defects -- perovskite solar cells -- solvent coordination; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201600575
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: We show the influence of species present in precursor solution during formation of lead halide perovskite materials on the structural defects of the films. The coordination of lead by competing solvent molecules and iodide ions dictate the type of complexes present in the films. Depending on the processing conditions all PbIS5 +, PbI2 S4, PbI3 S3 −, PbI4 S2 2−, PbI5 S2 3−, PbI6 4− and 1D (Pb2 I4 ) n chains are observed by absorption measurements. Different parameters are studied such as polarity of the solvent, concentration of iodide ions, concentration of solvent molecules and temperature. It is concluded that strongly coordinating solvents will preferentially form species with a low number of iodide ions and less coordinative solvents generate high concentration of PbI6 − . We furthermore propose that all these plumbate ions may act as structural defects determining electronic properties of the photovoltaic films. Abstract : Coordination needed : Structural defects are created during crystallization of perovskite materials depending on coordination ability of the solvents.