Modification of σ‐Donor Properties of Terminal Carbide Ligands Investigated Through Carbide–Iodine Adduct Formation. (9th September 2016)
- Record Type:
- Journal Article
- Title:
- Modification of σ‐Donor Properties of Terminal Carbide Ligands Investigated Through Carbide–Iodine Adduct Formation. (9th September 2016)
- Main Title:
- Modification of σ‐Donor Properties of Terminal Carbide Ligands Investigated Through Carbide–Iodine Adduct Formation
- Authors:
- Reinholdt, Anders
Vosch, Tom
Bendix, Jesper - Abstract:
- Abstract: The terminal carbide ligands in [(Cy3 P)2 X2 Ru≡C] complexes (X=halide or pseudohalide) coordinate molecular iodine, affording charge‐transfer complexes rather than oxidation products. Crystallographic and vibrational spectroscopic data show the perturbations of iodine to vary with the auxiliary ligand sphere on ruthenium, demonstrating the σ‐donor properties of carbide complexes to be tunable.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 40(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 40(2016)
- Issue Display:
- Volume 128, Issue 40 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 40
- Issue Sort Value:
- 2016-0128-0040-0000
- Page Start:
- 12672
- Page End:
- 12675
- Publication Date:
- 2016-09-09
- Subjects:
- Carbidliganden -- Gestaltung von Koordinationssphären -- Ladungstransfer -- Iod -- Ruthenium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201606551 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 64.xml