ChemInform Abstract: Palladium‐Catalyzed Stereospecific Allylation of Nitroacetates with Enantioenriched Primary Allylic Amines. Issue 41 (September 2016)

• Record Type: Journal Article
• Authors: Xu, Jing‐Kun; Wang, Yong; Gu, Yonghong; Tian, Shi‐Kai
• Is Part Of: ChemInform. Volume 47:Issue 41(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-09
• Subjects: nitro compounds (benzene compounds) -- C‐C bond formation -- decarboxylation -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201641089
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Nitroacetates undergo allylation with enantiopure allylic amines followed by one‐pot decarboxylation to afford homoallylic nitro compounds with excellent retention of configuration.