Valence states and possible charge ordering in LaCo1−xRhxO3. (8th February 2016)

• Record Type: Journal Article
• Authors: Streltsov, Sergey V; Gapontsev, Vladimir V; Khomskii, Daniel I
• Is Part Of: Journal of physics. Volume 28:Number 8(2016)
• Publication Date: 2016-02-08
• Subjects: cobaltates -- charge order -- redox reaction; Condensed matter -- Periodicals; Matière condensée -- Périodiques; Vaste stoffen; Vloeistoffen; Natuurkunde; Electronic journals; Computer network resources; 530.4105
• DOI: 10.1088/0953-8984/28/8/086005
• Languages: English
• ISSNs: 0953-8984

Abstract

Abstract: An unusual effect was discovered in Li et al (2010 J. Solid State Chem .183 1388): the substitution of nonmagnetic low-spin Co 3+ in LaCoO3 by the formally isoelectronic and also nonmagnetic Rh 3+ led, surprisingly, to a rapid appearance of magnetism in LaCo1− x Rh x O3, even for small amounts of doping. Different explanations for this effect were proposed in the literature. To clarify the situation we carried out unbiased ab initio calculations of this system. We concluded that, in agreement with the original assumption of Li et al, but in contrast with later statements (Knizek et al 2012 Phys. Rev . B85 134401), this effect is caused by the valence change ('redox reaction') Co 3+ + Rh 3+ Co 2+ + Rh 4+ , which creates magnetic Co 2+ and Rh 4+ ions. For the half-filled case LaCo1/2 Rh1/2 O3 we obtained the state with charge ordering of Co 2+ and Rh 4+ ions, which according to our calculations are antiferromagnetically coupled. The obtained results reasonably explain the observed behavior of the magnetic susceptibility of LaCo1− x Rh x O3, and the novel state predicted at half-doping could be verified experimentally by detailed structural and magnetic studies and by x-ray absorption spectroscopy.