ChemInform Abstract: Synthesis and Characterization of New Fluoride‐Containing Manganese Vanadates A2Mn2V2O7F2 (A: Rb, Cs) and Mn2VO4F. Issue 40 (September 2016)

• Record Type: Journal Article
• Authors: Sanjeewa, Liurukara D.; McGuire, Michael A.; Smith Pellizzeri, Tiffany M.; McMillen, Colin D.; Ovidiu Garlea, V.; Willett, Daniel; Chumanov, George; Kolis, Joseph W.
• Is Part Of: ChemInform. Volume 47:Issue 40(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-09
• Subjects: manganese, Mn -- fluorine, F -- alkali metals -- structure (solids and liquids); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201640018
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Single crystals of A2 Mn2 V2 O7 F2 (A: Rb, Cs) and Mn2 VO4 F are grown by high‐temperature hydrothermal reaction of stoichiometric amounts of Cs2 CO3 (Rb2 CO3 ), Mn2 O3, and V2 O5 together with CsF and RbF as mineralizers (Ag ampoules in water‐containing autoclave, 580 °C, 6—7 d).