ChemInform Abstract: Scandium‐Substituted Na3Zr2(SiO4)2(PO4) Prepared by a Solution‐Assisted Solid‐State Reaction Method as Sodium‐Ion Conductors. Issue 39 (September 2016)

• Record Type: Journal Article
• Authors: Ma, Qianli; Guin, Marie; Naqash, Sahir; Tsai, Chih‐Long; Tietz, Frank; Guillon, Olivier
• Is Part Of: ChemInform. Volume 47:Issue 39(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-09
• Subjects: zirconium, Zr -- scandium, Sc -- silicon, Si -- phosphorus, P -- electric properties, superconductors, semiconductors -- electrolytes, electrolytic conductivity (inorganic); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201639015
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Polycrystalline Na3+x Scx Zr2‐x (SiO4 )2 (PO4 ) (NSZSPx, x = 0—0.6) are fabricated on a laboratory scale (10 g—1 kg) by precipitation from stoichiometric aqueous solutions of NaNO3, Sc2 O3, ZrO(NO3 )2, Si(O‐Ac)4, and NH4 H2 PO4 followed by calcination (800 °C, 3 h), ball milling (2 d), and final sintering (1250—1300 °C, 5 h).