Bistable N–H⋯N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal. Issue 16 (11th April 2016)

• Record Type: Journal Article
• Authors: Ji, Chengmin; Li, Shenhui; Deng, Feng; Liu, Sijie; Asghar, Muhammad Adnan; Sun, Zhihua; Hong, Maochun; Luo, Junhua
• Is Part Of: Physical chemistry chemical physics. Volume 18:Issue 16(2016)
• Page Start: 10868
• Page End: 10872
• Publication Date: 2016-04-11
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c6cp01073c
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Bistable N–H⋯N hydrogen bonds enable the modulation of the dynamic molecular motion by slowing down the fast rotation in 1, 2-diazabicyclo(2.2.2)octane bis(thiourea). Abstract : Bistable N–H⋯N hydrogen bonds between rotors and stators enable delicate modulation of dynamic molecular motion by slowing down the fast rotation in a N–H⋯N hydrogen-bonded organic co-crystal of 1, 2-diazabicyclo(2.2.2)octane bis(thiourea), which has been elucidated by the combination of variable-temperature (VT) X-ray structure analyses and VT solid-state nuclear magnetic resonance techniques.