A mild, efficient, and selective procedure for the deoxygenation of sulfoxides with the TaCl5/indium system. (2nd June 2016)

• Record Type: Journal Article
• Authors: Yoo, Byung Woo; Lee, Min Kyung; Yoon, Cheol Min
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 191:Number 6(2016)
• Page Start: 807
• Page End: 810
• Publication Date: 2016-06-02
• Subjects: Deoxygenation -- sulfoxide -- sulfide -- tantalum(V) chloride -- indium; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2015.1119147
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: ABSTRACT: The TaCl5 /In system was found to be a new reagent for reducing a wide range of structurally diverse sulfoxides to the corresponding sulfides with high yields under mild conditions. This protocol is chemoselective and tolerates several functional groups, such as Br, Cl, OCH3, CHO, and CH = CH2 .