Viscoelasticity of Shear Thickening Fluid Based on Silica Nanoparticles Dispersing in 1-butyl-3-methylimidizolium Tetrafluoroborate. Issue 11 (1st November 2016)

• Record Type: Journal Article
• Authors: Qin, Jianbin; Zhang, Guangcheng; Shi, Xuetao
• Is Part Of: Journal of dispersion science and technology. Volume 37:Issue 11(2016)
• Page Start: 1599
• Page End: 1606
• Publication Date: 2016-11-01
• Subjects: 1-butyl-3-methylimidizolium tetrafluoroborate -- Clusters -- shear thickening fluid -- strain thickening -- viscoelasticity; Emulsions -- Periodicals; Suspensions (Chemistry) -- Periodicals; Emulsions; Suspensions; 541.34
• DOI: 10.1080/01932691.2015.1125297
• Languages: English
• ISSNs: 0193-2691

Abstract

Abstract : The viscoelasticity of shear thickening fluid (STF), a crucial property in the protective composite applications, with different silica nanoparticle concentrations in ionic liquid, 1-butyl-3-methylimidizolium tetrafluoroborate ([C4 min]BF4 ), was studied at different temperatures and with shear frequencies through oscillatory shear, respectively. All STFs present strain thickening behavior. With increasing silica nanoparticle concentration, the critical shear strain for the onset of strain thickening decreased, while the complex viscosity, storage modulus, and loss modulus increased significantly. The critical shear strain increased with an increase of temperature, while the complex viscosity, storage modulus, and loss modulus decreased notably. The critical shear strain was constant with increasing the frequency of strain, while the complex viscosity decreases slightly. The storage modulus and loss modulus were independent with frequency in the strain thickening region. Nanoparticle clusters leading to strain thickening were demonstrated. The viscoelastic response of STFs to varying silica nanoparticle content, temperature, and frequency investigated here will help to design the specific application of STFs in soft protective composites and damping devices. GRAPHICAL ABSTRACT: