Experimental studies and model validation for the optimization of electrodes configuration in a molten salt electrorefiner. Issue 8 (23rd May 2016)

• Record Type: Journal Article
• Authors: Srihari, B. Krishna; Reddy, B. Prabhakara; Venkatesh, P.; Agarwal, S.; Sai, P.M. Satya; Nagarajan, K.
• Is Part Of: Separation science and technology. Volume 51:Issue 8(2016)
• Page Start: 1397
• Page End: 1407
• Publication Date: 2016-05-23
• Subjects: Cell resistance -- COMSOL Multiphysics -- electrode configuration -- liquid cadmium anode -- molten salt; Separation (Technology) -- Periodicals; 660.284205
• DOI: 10.1080/01496395.2016.1158190
• Languages: English
• ISSNs: 0149-6395

Abstract

ABSTRACT: Molten salt electrorefining is a high-temperature electrochemical process for treating the spent metallic fuel from fast reactors and is aimed at the separation of U and Pu from fission products. Potential and current distribution analysis was carried out by experimental studies as well as modelling using COMSOL Multiphysics for various electrode configurations. A 2D/2D axisymmetric geometry model was used to evaluate the potential and current distributions. The effect of the following parameters was evaluated: (1) configuration having two pairs of electrodes in parallel/staggered arrangement; (2) centre-to-centre distance between the electrodes; (3) solid cathode with and without insulation at the bottom; (4) Cd cathode and (5) cathode surface area. The resistance of the electrorefiner was calculated using COMSOL model for various electrode configurations and compared with that obtained experimentally. There was very good agreement between the experimental values and the simulation results. The computed cell resistance was also validated with published data. A sensitivity analysis was also performed to determine the parameter that more significantly influences the cell resistance. The two parameters that were varied were the electrolyte conductivity and the cell voltage. It is observed that of the two parameters the cell resistance is most sensitive to the electrolyte conductivity and there is no change in cell resistance with cell voltage.