Construction of four d10 coordination polymers containing binuclear rings as building blocks from 4′-(2H-tetrazol-5-yl)biphenyl-4-carboxylic acid. Issue 6 (18th March 2016)

• Record Type: Journal Article
• Authors: Li, Tian-Tian; Wen, Zhen-Zhen; Cai, Song-Liang; Zheng, Sheng-Run
• Is Part Of: Journal of coordination chemistry. Volume 69:Issue 6(2016)
• Page Start: 976
• Page End: 984
• Publication Date: 2016-03-18
• Subjects: 4′-(2H-tetrazol-5-yl)biphenyl-4-carboxylic acid -- coordination polymer -- luminescent property; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2016.1147563
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: Four coordination polymers based on 4′-(2H-tetrazol-5-yl)biphenyl-4-carboxylic acid (H2 TBPC), [Zn(μ3 -TBPC)(H2 O)]n (1 ), [Zn(μ3 -TBPC)(Me2 NH)]n (2 ), [Cd(μ3 -TBPC)(bpy)]n (bpy = 4, 4′-bipyridine, 3 ), and [Cd(μ4 -TBPC)(H2 O)]n (4 ), were constructed under hydrothermal conditions. The compounds are composed of M2 (TBPC)2 binuclear ring as a building block. In1 –3, the binuclear rings are interconnected to three different 2-D networks with the same (4·8 2 ) topology. In4, the binuclear rings are arranged into a 3-D framework with PtS-type topology. The results revealed that the structural diversity is mainly attributed to the coordination geometries of metal ion, the coordination modes of TBPC 2−, and the auxiliary ligand. The thermal stabilities and luminescent properties of1 –4 have also been studied. Abstract :