A convenient method for reduction dehalogenation of α-halocarbonyl compounds using benzenethiol in K+/CH3CN system. (2nd July 2016)

• Record Type: Journal Article
• Authors: Dong, Wei-Li; Cai, Wen-Xi; Wu, Rui; Li, Zheng-Ming; Zhao, Wei-Guang; Liu, Xing-Hai
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 191:Number 7(2016)
• Page Start: 980
• Page End: 983
• Publication Date: 2016-07-02
• Subjects: Benzenethiol -- α-halocarbonyl -- dehalogenation -- K+/CH3CN; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2016.1138309
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: ABSTRACT: Benzenethiol, as a reductive agent for the dehalogenation of various α-halocarbonyl compounds, is investigated in the K + /CH3 CN system. The reaction affords the reduced compounds in high yields under mild reaction conditions, especially α-chlorocarbonyl compounds. Furthermore, the reaction performed under ultrasonic irradiation greatly shortens the reaction time.