Fabrication of nano-grained Ti–Nb–Zr biomaterials using spark plasma sintering. (15th December 2015)

• Record Type: Journal Article
• Authors: Hussein, M.A.; Suryanarayana, C.; Al-Aqeeli, N.
• Is Part Of: Materials & design. Volume 87(2015:Dec.)
• Page Start: 693
• Page End: 700
• Publication Date: 2015-12-15
• Subjects: Biomaterials -- Spark plasma sintering -- Mechanical alloying -- Nanomaterials -- Ti–Nb–Zr alloy; Materials -- Periodicals; Engineering design -- Periodicals; Matériaux -- Périodiques; Conception technique -- Périodiques; Electronic journals; 620.11
• DOI: 10.1016/j.matdes.2015.08.082
• Languages: English
• ISSNs: 0264-1275

Abstract

Abstract: Nanostructured near-β Ti–20Nb–13Zr at % alloy with non-toxic elements and enhanced mechanical properties has been synthesized by spark plasma sintering (SPS) of nanocrystalline powders obtained by mechanical alloying. The consolidated bulk product was characterized by density measurements and Vickers hardness (HV), and X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) combined with energy-dispersive spectroscopy (EDX), and transmission electron microscopy (TEM) for structural details. The temperature during spark plasma sintering was varied between 800 and 1200 °C, while the heating rate and holding time of 100°K/min and 10 min were maintained constant in all the experiments. The effect of SPS temperature on the densification, microstructure, and HV was discussed. The results show that a nearly full density structure was obtained after SPS at 1200 °C. The microstructure of the obtained alloy is a duplex structure with the α-Ti (hcp) region having an average size of 70–140 nm, surrounding the β-Ti (bcc) matrix. The obtained alloy was chemically homogenized with a micro hardness value, HV of 660. The developed nanostructured Ti–20Nb–13Zr alloy is suggested for biomedical use as in implant material in dental and orthopedic applications. Graphical abstract: Highlights: A novel preparation route is reported for nano-grained near-β Ti–20Nb–13Zr at % alloy MA + SPS. Nano grains of 100–300 nm and hardness of 660 HV were obtained. The microstructure of the obtained alloy is a duplex structure with the α-Ti (hcp) region surrounding the β-Ti (bcc) matrix. The developed nano-grained alloy is candidate for use as in implant material in dental and orthopedic applications.