A New Zn(II) Coordination Polymer With (3, 4)-Connected 3, 4T10 Topological Net Based on Pyromellitic Acid and N-Donor ligand: Synthesis, Crystal Structure, and Luminescent Property. Issue 8 (2nd August 2016)

• Record Type: Journal Article
• Authors: Yang, Lili
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 8(2016)
• Page Start: 1198
• Page End: 1201
• Publication Date: 2016-08-02
• Subjects: Zn(II) -- coordination polymer -- crystal structure; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1004446
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A new coordination polymer, {[Zn(H2 btec)(bpmp)]·2H2 O}n (1 )(H4 btec = 1, 2, 4, 5-benzenetetracarboxylic acid and bpmp = 1, 4-bis(4-pyridylmethy) piperazine) has been prepared by hydrothermal synthesis and characterized by elemental analysis, IR and X-ray diffraction. Complex {[Zn(H2 btec)(bpmp)]·2H2 O}n (1 ), monoclinic, space group P 21 /n with a = 10.014 (5) Å, b = 13.448 (5) Å, c = 14.550 (5) Å, β = 97.349 (5)° V = 1943.3 (14) Å 3, Z = 4, Mr = 486.74, Dc = 1.664g/cm 3, F (000) = 998 and µ = 1.326 mm −1 . The final refinement gave R = 0.0356and wR = 0.0958for 4471 reflections with I > 2σ( I ). X-ray diffraction analysis reveals that complex 1 shows a three-dimensional (3, 4)-connected 3, 4T10 topological net.