Assembly and Selective Photocatalysis of Two Multifunctional Copper(II) Complexes Derived From a Bis-Pyridyl-Bis-Amide and Two Dicarboxylates. Issue 9 (1st September 2016)

• Record Type: Journal Article
• Authors: Wang, Xiu-Li; Le, Mao; Lin, Hong-Yan; Luan, Jian; Liu, Guo-Cheng
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 9(2016)
• Page Start: 1381
• Page End: 1387
• Publication Date: 2016-09-01
• Subjects: metal-organic coordination polymers -- semirigid bis-pyridyl-bis-amide ligand -- crystal structures -- electrochemistry -- photocatalysis; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1136957
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : Two multifunctional metal-organic coordination polymers, namely [Cu(4-bpah)(2, 6-PDA)] (1 ) and [Cu(4-bpah)(3-NIP)]·H2 O (2 ), where 4-bpah = N, N ′-bis(4-pyridinecarboxamide)-1, 2-cyclohexane, 2, 6-H2 PDA = pyridine-2, 6-dicarboxylic acid, 3-H2 NIP = 3-nitrophalic acid, have been hydrothermally synthesized and structurally characterized by IR, TG, and single-crystal X-ray diffraction analyses. Complex1 is a 1D infinite helix chain structure. Complex2 possesses a 2D polymeric layer containing two kinds of meso -helical chains: [Cu-4-bpah]n and [Cu-3-NIP]n . The adjacent 1D chains for1 or the adjacent 2D layers for2 are further linked by hydrogen bonding interactions to form 2D or 3D supramolecular networks, respectively. The fluorescent, electrochemical and photocatalytic properties of complexes1–2 have also been investigated.