(5, 6)-Connected 3D Metal–Organic Framework Based on Terphenyl-3, 2″, 5″, 3′-tetracarboxylate: Synthesis, Structures, and Properties. Issue 9 (1st September 2016)

• Record Type: Journal Article
• Authors: Wang, Hua-Rui; Liu, Shi-Jiang
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 9(2016)
• Page Start: 1422
• Page End: 1425
• Publication Date: 2016-09-01
• Subjects: tetracarboxylate -- assemble -- topology -- metal–organic framework; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1137008
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : One metal–organic framework [Mn(tptc)0.5 (bpp)] (1 ) (H4 tptc = terphenyl-3, 2″, 5″, 3′-tetracarboxylic acid, bpp = 1, 3-bis(4-pyridyl)propane) has been synthesized by the reaction of a tetracarboxylate and auxiliary pyridine-based ligands with Mn(II) ion under hydrothermal conditions. This complex was further studied by elemental analysis, IR spectroscopy, and X-ray crystallography. In the structure of1, the alternately assembled 2D helical bilayers and pyridine pillars gives rise to a rare (5, 6)-connected 3D pillared helical-layer MOF. In addition, thermal gravimetric analysis of1 was also investigated.