Gas Adsorption and Luminescent Properties of a Porous pcu-Type Zn(II) Coordination Polymer. Issue 12 (1st December 2016)

• Record Type: Journal Article
• Authors: An, Zhe; Wang, Jian
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 12(2016)
• Page Start: 1810
• Page End: 1814
• Publication Date: 2016-12-01
• Subjects: Zn(II) compound -- 2, 5-thiophenedicarboxylic acid -- pillar-layered framework -- luminescence; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1137061
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A new Zn(II) compound, namely {Zn2 (tdc)2 (pi)}n (1 H2 tdc = 2, 5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3 )2 ·6H2 O, H2 tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic P nma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of1 were investigated in the solid state at room temperature.