Synthesis, Crystal Structure, and Fluorescent Property of an Ag(I) Complex With 3-(Benzoimidazol-2-yl)propanoic Acid. Issue 12 (1st December 2016)

• Record Type: Journal Article
• Authors: Fu, Wei-Wei; Liu, Ying-Ying; Zhang, Yan-Hua; Xu, Liu; Zhang, Jun-Lan; Wei, Hai-Bo
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 12(2016)
• Page Start: 1857
• Page End: 1860
• Publication Date: 2016-12-01
• Subjects: silver(I) complex -- crystal structure -- fluorescent property; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1137017
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A silver complex, Ag(L)(2, 2′-bpy)(H2 O)2 (1 ), has been synthesized with 3-(benzoimidazol-2-yl)propanoic acid (HL) and 2, 2′-bipyridine (2, 2′-bpy) and characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction. The complex crystallizes in monoclinic system with space group P2(1)/c, a = 10.6088(4), b = 12.3566(3), c = 15.3319(5) Å, β = 101.668(4)°, V = 1968.31(11) Å 3, Dc = 1.634 g/cm 3, Z = 4, F (000) = 972, final GOF = 1.058, R = 0.0334, and wR = 0.0895 for 3469 observed reflections with I > 2σ(I) . The crystal structure analysis shows that a three dimensional network was formed by hydrogen bonds and π-π interactions. The fluorescence property of1 has been investigated.