C‐Propargylation Overrides O‐Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium‐Catalyzed Transfer Hydrogenation. (20th June 2016)

Record Type:: Journal Article
Title:: C‐Propargylation Overrides O‐Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium‐Catalyzed Transfer Hydrogenation. (20th June 2016)
Main Title:: C‐Propargylation Overrides O‐Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium‐Catalyzed Transfer Hydrogenation
Authors:: Liang, Tao
Woo, Sang Kook
Krische, Michael J.
Abstract:: Abstract: The canonical SN 2 behavior displayed by alcohols and activated alkyl halides in basic media (O‐alkylation) is superseded by a pathway leading to carbinol C‐alkylation under the conditions of rhodium‐catalyzed transfer hydrogenation. Racemic and asymmetric propargylations are described.
Is Part Of:: Angewandte Chemie. Volume 128:Number 32(2016)
Journal:: Angewandte Chemie
Issue:: Volume 128:Number 32(2016)
Issue Display:: Volume 128, Issue 32 (2016)
Year:: 2016
Volume:: 128
Issue:: 32
Issue Sort Value:: 2016-0128-0032-0000
Page Start:: 9353
Page End:: 9357
Publication Date:: 2016-06-20
Subjects:: Alkohole -- Hydrierungen -- Reaktionsmechanismen -- Rhodium -- Synthesemethoden
Chemistry -- Periodicals
540
Journal URLs:: http://onlinelibrary.wiley.com/ ↗
DOI:: 10.1002/ange.201603575 ↗
Languages:: English
ISSNs:: 0044-8249
Deposit Type:: Legaldeposit
View Content:: Available online (eLD content is only available in our Reading Rooms) ↗
Physical Locations:: British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store
Ingest File:: 1472.xml