Inside Back Cover: First Step Towards a Devil's Staircase in Spin‐Crossover Materials (Angew. Chem. Int. Ed. 30/2016). Issue 30 (12th May 2016)

• Record Type: Journal Article
• Authors: Trzop, Elzbieta; Zhang, Daopeng; Piñeiro‐Lopez, Lucia; Valverde‐Muñoz, Francisco J.; Carmen Muñoz, M.; Palatinus, Lukas; Guerin, Laurent; Cailleau, Hervé; Real, Jose Antonio; Collet, Eric
• Is Part Of: Angewandte Chemie international edition. Volume 55:Issue 30(2016)
• Page Start: 8767
• Page End: 8767
• Publication Date: 2016-05-12
• Subjects: aperiodicity -- coordination polymers -- Devil's staircase -- phase transitions -- spin-crossover; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201604286
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : The devil is in the detail Periodic and aperiodic spin‐state concentration waves form during "Devil's staircase"‐type spin‐crossover in a new bimetallic 2D coordination polymer {Fe[(Hg(SCN)3 )2 ](4, 4′‐bipy)2 } n . In their Communication onpage 8675 ff., J. A. Real, E. Collet et al. describe the appearance of spin‐state concentration waves between long‐range spatially ordered structures of low‐ and high‐spin states during multistep spin‐crossover.