Ion‐Free and Ion‐Pairing Assemblies of Anion‐Responsive π‐Electronic Systems Possessing Directly Linked Alkyl Chains. Issue 14 (30th June 2016)

• Record Type: Journal Article
• Authors: Haketa, Yohei; Katayama, Daisuke; Fukunaga, Shinya; Bando, Yuya; Sakurai, Tsuneaki; Matsuda, Wakana; Seki, Shu; Maeda, Hiromitsu
• Is Part Of: Chemistry, an Asian journal. Volume 11:Issue 14(2016)
• Page Start: 2025
• Page End: 2029
• Publication Date: 2016-06-30
• Subjects: anion binding -- assembled structures -- ion pairs -- pyrrole derivatives -- π-electronic molecules; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201600712
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: Alkyl‐substituted pyrrole‐based anion‐responsive π‐electronic systems formed supramolecular gels and liquid crystals through effective π–π stacking and van der Waals interactions. The addition of chloride as a planar cation salt afforded ion‐pairing assemblies as soft materials comprising planar receptor‐Cl − complexes and the cation. Abstract : Always responsive : Alkyl‐substituted pyrrole‐based anion‐responsive π‐electronic systems formed supramolecular gels and liquid crystals through effective π–π stacking and van der Waals interactions. The addition of chloride as a planar cation salt afforded ion‐pairing assemblies as soft materials comprising planar receptor‐Cl − complexes and the cation.