ChemInform Abstract: Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides. Issue 34 (4th August 2016)

• Record Type: Journal Article
• Authors: Zhang, Qingnan; Hu, Shu‐Xian; Qu, Hui; Su, Jing; Wang, Guanjun; Lu, Jun‐Bo; Chen, Mohua; Zhou, Mingfei; Li, Jun
• Is Part Of: ChemInform. Volume 47:Issue 34(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-08-04
• Subjects: praseodymium, Pr -- oxygen, O -- theory, structure -- IR and Raman spectra (atoms and molecules); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201634016
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The complex (μ 2 ‐O2 )PrO2 and the linear core‐containing PrO2 + complexes are observed both in the gas phase by laser vaporization of Pr in He2 seeded with a pulsed 30—40% O2 stream (1‐1.2 MPa) and in solid Ar matrices analyzed by matrix isolation IR and IR photodissociation spectroscopy (0.2—0.5 mJ/pulse, 850—1600 cm ‐1 ) with TOF‐MS‐selected [(PrO2 ) + (O2 )n ] cations.