ChemInform Abstract: Catalytic Diazosulfonylation of Enynals Toward Diazoindenes via Oxidative Radical‐Triggered 5‐exo‐trig Carbocyclizations. Issue 34 (4th August 2016)

• Record Type: Journal Article
• Authors: Hao, Wen‐Juan; Du, Yan; Wang, Dan; Jiang, Bo; Gao, Qian; Tu, Shu‐Jiang; Li, Guigen
• Is Part Of: ChemInform. Volume 47:Issue 34(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-08-04
• Subjects: indan derivatives -- ring closure reactions, annulation reactions -- radical reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201634097
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The novel diazosulfonation reaction proceeds via addition of sulfonyl radicals to the enynal triple bond followed by 5‐exo‐trig carbocyclization/H‐abstraction sequence to furnish unprecedented diazoindenyl sulfones.