An enhanced extended hook method to realize tetranuclear metal clusters embedded in energetic metal–organic framework channels. Issue 31 (13th July 2016)

• Record Type: Journal Article
• Authors: Xiao, Yu; Wang, Shuai-Hua; Xu, Jian-Gang; Sun, Cai; Li, Rong; Zhao, Ya-Ping; Yan, Yong; Zheng, Fa-Kun; Guo, Guo-Cong
• Is Part Of: CrystEngComm. Volume 18:Issue 31(2016)
• Page Start: 5803
• Page End: 5806
• Publication Date: 2016-07-13
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c6ce00892e
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Rare tetranuclear Zn clusters were successfully embedded into energetic 3D metal–organic framework channels by an extended bifunctional tetrazolate–carboxylate hook ligand. Abstract : Rare tetranuclear Zn clusters were successfully embedded into 3D energetic metal–organic framework channels by an enhanced extended hook method. The obtained metal–organic framework exhibits not only high enthalpy of combustion and low sensitivity but also strong green fluorescence.