A novel oxime-derived 3d–4f single-molecule magnet exhibiting two single-ion magnetic relaxations. Issue 29 (5th July 2016)

• Record Type: Journal Article
• Authors: Dong, Hui-Ming; Li, Yan; Liu, Zhong-Yi; Yang, En-Cui; Zhao, Xiao-Jun
• Is Part Of: Dalton transactions. Volume 45:Issue 29(2016)
• Page Start: 11876
• Page End: 11882
• Publication Date: 2016-07-05
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt02003h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A weak ferromagnetic coupled {Dy4 Ni6 } cluster with a butterfly-shaped DyIII4 core and four-coordinate diamagnetic Ni II ions shows field-induced SMM behaviour with two overlapping thermally activated relaxations. Abstract : A new oxime-derived {DyIII4NiII6} cluster with a paramagnetic butterfly-shaped DyIII4 core and peripheral diamagnetic planar-square Ni II ions was solvothermally synthesized. The weak ferromagnetically coupled cluster exhibits field-induced single-molecule magnetic behavior with two thermally activated single-ion relaxations.