Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical. Issue 28 (30th June 2016)

• Record Type: Journal Article
• Authors: Cao, Jiamei; Feng, Yongqiang; Zhou, Shengju; Sun, Xiaofeng; Wang, Taishan; Wang, Chunru; Li, Hongguang
• Is Part Of: Dalton transactions. Volume 45:Issue 28(2016)
• Page Start: 11272
• Page End: 11276
• Publication Date: 2016-06-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt01735e
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The effect of two typical metal–organic frameworks (MOF-177 and MIL-53) with a distinctive aperture size and spatial geometry on the electron spin properties of a spin-labeled fullerene was investigated. Abstract : The electron spin properties of a fulleropyrrolidine nitroxide radical incarcerated in the pores of MOF-177 and MIL-53 respectively were investigated for the first time. It was found that the spatial confinement effect and intramolecular interactions in these two solid-state spin systems lead to dramatically distinctive spin dynamics.