Electrochemical fabrication of silver tips for tip‐enhanced Raman spectroscopy assisted by a machine vision system. (22nd February 2016)

• Record Type: Journal Article
• Authors: Li, Maohua; Lv, Ruiqi; Huang, Shengchao; Dai, Yinzhen; Zeng, Zhicong; Wang, Lei; Ren, Bin
• Is Part Of: Journal of Raman spectroscopy. Volume 47:Number 7(2016)
• Page Start: 808
• Page End: 812
• Publication Date: 2016-02-22
• Subjects: silver tips -- tip‐enhanced Raman spectroscopy -- machine vision system -- electrochemical etching; Raman spectroscopy -- Periodicals; 535.846
• DOI: 10.1002/jrs.4898
• Languages: English
• ISSNs: 0377-0486

Abstract

Abstract : Both tip‐enhanced Raman spectroscopy and scanning tunneling microscopy require the use of sharp tips. Electrochemical etching appears to be the most widely used method for preparing tips. To address the over‐etching problem associated with the silver tips by either using voltage or current as a feedback, we developed here an optical method‐based machine vision to achieve a quick cutoff of the circuit once the tip forms. It is a fully automated method with a response time of about 40 ms and is tolerated with any existing electrochemical etching method. We can significantly decrease the time of over‐etching of the silver tip when short rectangular pulses with a duty cycle of 28.6% were used. The mean radius of curvature was ca. 58 nm, as measured from over 50 tips. The capacities of silver tips for high‐resolution scanning tunneling microscopy imaging and high‐sensitivity tip‐enhanced Raman studies have been demonstrated. Copyright © 2016 John Wiley & Sons, Ltd. Abstract : A machine vision system was developed to control the electrochemical etching of silver wire. Silver tips with a mean radius of ca. 58 nm were fabricated and demonstrated to be well suitable for high‐resolution scanning tunneling microscopy imaging and high‐sensitivity tip‐enhanced Raman studies.