Nitrogen‐Doped Ordered Mesoporous Carbon Supported Bimetallic PtCo Nanoparticles for Upgrading of Biophenolics. (13th June 2016)

• Record Type: Journal Article
• Authors: Wang, Guang‐Hui; Cao, Zhengwen; Gu, Dong; Pfänder, Norbert; Swertz, Ann‐Christin; Spliethoff, Bernd; Bongard, Hans‐Josef; Weidenthaler, Claudia; Schmidt, Wolfgang; Rinaldi, Roberto; Schüth, Ferdi
• Is Part Of: Angewandte Chemie. Volume 128:Number 31(2016)
• Page Start: 8996
• Page End: 9001
• Publication Date: 2016-06-13
• Subjects: Biomasse -- Dimetallnanopartikel -- Hydrodesoxygenierung -- Mesoporöse Materialien -- Phenole; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201511558
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Hydrodeoxygenation (HDO) is an attractive route for the upgrading of bio‐oils produced from lignocellulose. Current catalysts require harsh conditions to effect HDO, decreasing the process efficiency in terms of energy and carbon balance. Herein we report a novel and facile method for synthesizing bimetallic PtCo nanoparticle catalysts (ca. 1.5 nm) highly dispersed in the framework of nitrogen‐doped ordered mesoporous carbon (NOMC) for this reaction. We demonstrate that NOMC with either 2D hexagonal ( p 6 m ) or 3D cubic ( Im 3 ‾ m ) structure can be easily synthesized by simply adjusting the polymerization temperature. We also demonstrate that PtCo/NOMC (metal loading: Pt 9.90 wt %; Co 3.31 wt %) is a highly effective catalyst for HDO of phenolic compounds and "real‐world" biomass‐derived phenolic streams. In the presence of PtCo/NOMC, full deoxygenation of phenolic compounds and a biomass‐derived phenolic stream is achieved under conditions of low severity.