Synthesis, Crystal Structure, and Properties of a New Zinc(II) Coordination Polymer With Mixed 4, 4′-biphenyldisulfonic Acid and N-Donor Ligands. Issue 12 (1st December 2016)

• Record Type: Journal Article
• Authors: Lermontova, Elmira Kh.; Yang, Guo-Ping; Wang, Xun-Ming; Wang, Yao-Yu; Shi, Qi-Zhen
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 12(2016)
• Page Start: 1815
• Page End: 1818
• Publication Date: 2016-12-01
• Subjects: complex -- crystal structures -- H-bonded interaction -- properties -- sulfonic group; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2011.614999
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A new zinc(II) coordination polymer, namely [Zn(bipy)2 (H2 O)4 ] n · n (dsba) (1), has been synthesized by the mixed 4, 4′-biphenyldisulfonic acid (H2 dsba) and 4, 4′-bipyridine (bipy) ligands with Zinc(II) salt under the common solution evaporation method. The results of the X-ray crystal diffraction analysis show that complex 1 belongs to the monoclinic system with P21 /c space group. The unit cell constants of complex 1 are a = 9.2579 Å, b = 12.2016 Å, c = 14.447 Å, α = γ = 90˚, β = 93.476˚. Complex 1 exhibits a three-dimensional supramolecular network based on the discrete structure by utilizing various H-bonded interactions. In addition, the properties of complex 1, such as the elemental analysis, FT-IR spectroscopy, X-ray powder diffraction, and fluorescence spectroscopy were also characterized and are discussed in detailed.