Synthesis, crystal structures, and magnetic properties of double perovskites SrLaNiOsO6 and BaLaNiOsO6. (October 2016)

• Record Type: Journal Article
• Authors: Feng, Hai L.; Schnelle, Walter; Tjeng, Liu Hao; Jansen, Martin
• Is Part Of: Solid state communications. Volume 243(2016)
• Page Start: 49
• Page End: 54
• Publication Date: 2016-10
• Subjects: A. Ni2+-Os5+ -- A. Double perovskite -- C. Structure distortion -- D. Magnetic property; Solid state chemistry -- Periodicals; Solid state physics -- Periodicals; Chimie de l'état solide -- Périodiques; Physique de l'état solide -- Périodiques; 530.41
• DOI: 10.1016/j.ssc.2016.06.008
• Languages: English
• ISSNs: 0038-1098

Abstract

Abstract: New double perovskite oxides SrLaNiOsO6 and BaLaNiOsO6 were synthesized by solid state reactions from the respective binary metal oxides, and their crystal structures and magnetic properties were characterized. At room temperature SrLaNiOsO6 and BaLaNiOsO6 crystallize in ordered double perovskite structures with space groups of P 21 / n (monoclinic) and I 4/ m (tetragonal), respectively. They are electrically semiconducting with an activation energy of ≈0.35 eV. Specific heat and magnetic measurements indicate that SrLaNiOsO6 shows predominantly antiferromagnetic correlations and displays antiferromagnetic transition around 60 K. However, for the isoelectronic BaLaNiOsO6 ferromagnetic correlations are predominant and there is no clear feature of a magnetic transition detectable. The remarkable change in magnetic properties of A LaNiOsO6 ( A = Sr and Ba) can be related to the degree of structure distortions, i.e. the bending of the O- B -O ( B = Ni, Os) links. Highlights: New 3d-5d double perovskites SrLaNiOsO6 and BaLaNiOsO6 were synthesized. AF interactions dominate in SrLaNiOsO6, but FM interactions in BaLaNiOsO6 . The different magnetic properties can be related to the local lattice distortions.