Intramolecular cationic cyclization of β-hydroxyalkylphosphine oxides—a route towards the benzophosphorinane core. Issue 33 (18th August 2016)
- Record Type:
- Journal Article
- Title:
- Intramolecular cationic cyclization of β-hydroxyalkylphosphine oxides—a route towards the benzophosphorinane core. Issue 33 (18th August 2016)
- Main Title:
- Intramolecular cationic cyclization of β-hydroxyalkylphosphine oxides—a route towards the benzophosphorinane core
- Authors:
- Włodarczyk, Katarzyna
Stankevič, Marek - Abstract:
- Abstract: Intramolecular cationic cyclization of β-hydroxyalkylphosphine oxides in the presence of an acid lead to the formation of fused bicyclic compounds with an incorporated phosphorus atom. Depending on the structure of the starting compound the formation of either phosphaindane or benzophosphorinane oxides has been observed. The key difference in the reactivity arises from the substitution pattern at the carbinolic carbon atom of β-hydroxyalkylphosphine oxide. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 33(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 33(2016)
- Issue Display:
- Volume 72, Issue 33 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 33
- Issue Sort Value:
- 2016-0072-0033-0000
- Page Start:
- 5074
- Page End:
- 5090
- Publication Date:
- 2016-08-18
- Subjects:
- β-Hydroxyalkylphosphine oxide -- Intramolecular -- Cationic cyclization -- Phosphaindane -- Benzophosphorinane
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.06.070 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 775.xml