Catalyst-controlled switch of regioselectivity in the asymmetric allylic alkylation of oxazolones with MBHCs. Issue 50 (2nd June 2016)
- Record Type:
- Journal Article
- Title:
- Catalyst-controlled switch of regioselectivity in the asymmetric allylic alkylation of oxazolones with MBHCs. Issue 50 (2nd June 2016)
- Main Title:
- Catalyst-controlled switch of regioselectivity in the asymmetric allylic alkylation of oxazolones with MBHCs
- Authors:
- Zhu, Gongming
Yang, Junxian
Bao, Guangjun
Zhang, Ming
Li, Jing
Li, Yiping
Sun, Wangsheng
Hong, Liang
Wang, Rui - Abstract:
- Abstract : A catalyst-controlled switch of regioselectivity in asymmetric allylic alkylation of oxazolones with MBHCs was described. Abstract : A catalyst-controlled switch of regioselectivity in asymmetric allylic alkylation of oxazolones with MBHCs was described. The SN 2′–SN 2′ reaction catalysed by a quinine-derived base produced γ-selective secondary allylic oxazolone derivatives, whereas the addition–elimination reaction catalysed by an amino acid-derived bifunctional urea catalyst provided β-selective primary adducts.
- Is Part Of:
- Chemical communications. Volume 52:Issue 50(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 50(2016)
- Issue Display:
- Volume 52, Issue 50 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 50
- Issue Sort Value:
- 2016-0052-0050-0000
- Page Start:
- 7882
- Page End:
- 7885
- Publication Date:
- 2016-06-02
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc03246j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2466.xml