Controlling dielectrical properties of polymer blends through defined PEDOT nanostructures. Issue 66 (28th June 2016)

• Record Type: Journal Article
• Authors: Sanchis, Maria J.; Redondo-Foj, Belén; Carsí, Marta; Ortiz-Serna, Pilar; Culebras, Mario; Gómez, Clara M.; Cantarero, Andrés; Muñoz-Espí, Rafael
• Is Part Of: RSC advances. Volume 6:Issue 66(2016)
• Page Start: 62024
• Page End: 62030
• Publication Date: 2016-06-28
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra05597d
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The paper reports the crucial role of the morphology of poly(3, 4-ethylenedioxythiophene) (PEDOT) nanostructures on the thermal and dielectric properties of polymer blends prepared thereof. Abstract : The paper reports the crucial role of the morphology of poly(3, 4-ethylenedioxythiophene) (PEDOT) nanostructures on the thermal and dielectric properties of polymer blends prepared thereof. PEDOT nanostructures with two different morphologies (nanoparticles and nanowires) were synthesized. The size for the nanoparticles was in the range 10–40 nm and the diameter of the nanowires was of ca. 200 nm. These nanostructures were blended with an insulating polymer matrix, poly(methyl methacrylate) (PMMA), to evaluate the dielectrical properties of the materials. The results of broadband dielectric spectroscopy showed a strong correlation between the morphology of the nanostructure and the improvement of the electrical properties of the material.