ChemInform Abstract: Iodobismuthates Containing One‐Dimensional BiI4‐ Anions as Prospective Light‐Harvesting Materials: Synthesis, Crystal and Electronic Structure, and Optical Properties. Issue 29 (June 2016)

• Record Type: Journal Article
• Authors: Yelovik, Natalie A.; Mironov, Andrei V.; Bykov, Mikhail A.; Kuznetsov, Alexey N.; Grigorieva, Anastasia V.; Wei, Zheng; Dikarev, Evgeny V.; Shevelkov, Andrei V.
• Is Part Of: ChemInform. Volume 47:Issue 29(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-06
• Subjects: electric properties, superconductors, semiconductors -- optical properties (excluding spectra) (solids and liquids) -- energy conversion -- bismuth, Bi -- iodine, I -- alkali metals -- manganese, Mn; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201629006
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: In the frame of replacing toxic Pb of iodoplumbates in all‐solid, dye‐sensitized solar cells, LiBiI4 ·5H2 O (I), MgBi2 I8 ·8H2 O (II), MnBi2 I8 ·8H2 O (III), and KBiI4 ·H2 O (IV) are prepared by solvent evaporation of solutions containing e.g. BiI3 and Li2 CO3 (2:1) in freshly prepared HI (5 weeks under ambient air, ≈70% yield).