Syntheses, crystal structures and luminescent properties of two new Zn(II) coordination polymers based on a dicarboxylate and different imidazole-containing ligands. Issue 10 (18th May 2016)

• Record Type: Journal Article
• Authors: Feng, Xiuling; Chen, Wanping; Xiang, Bolin
• Is Part Of: Journal of coordination chemistry. Volume 69:Issue 10(2016)
• Page Start: 1551
• Page End: 1558
• Publication Date: 2016-05-18
• Subjects: Zn(II) -- crystal structure -- luminescence; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2016.1179289
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: To investigate the effect of different imidazole-containing ligands on the structure of coordination polymers, two new Zn(II) coordination polymers based on 1, 4-cyclohexanedicarboxylic acid (H2 cda) and two different imidazole-containing ligands, [Zn(cda)(bib)0.5 ]n (1 ) and [Zn(cda)(bmib)0.5 ]n (2 ) (bib = 1, 4-bis(imidazol-1-yl)benzene and bmib = 1, 4-bis(2-methylimidazol-3-ium-yl)benzene), have been synthesized and characterized by single-crystal X-ray diffraction. Complex1 shows a 3-D structure with point symbol (4.8 2 .10 3 ).(4.8 2 ). Complex2 displays a 2-D layer structure with an –AB– stacking sequence. Abstract :