Polyoxometalate Cluster‐Incorporated Metal‐Organic Framework Hierarchical Nanotubes. Issue 22 (21st April 2016)

• Record Type: Journal Article
• Authors: Xu, Xiaobin; Chen, Shuangming; Chen, Yifeng; Sun, Hongyu; Song, Li; He, Wei; Wang, Xun
• Is Part Of: Small. Volume 12:Issue 22(2016)
• Page Start: 2982
• Page End: 2990
• Publication Date: 2016-04-21
• Subjects: catalysis -- hierarchical structures -- lithium‐ion batteries -- metal‐organic frameworks; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201503695
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract : A simple method to prepare metal‐organic framework (MOF) nanotubes is developed by employing polyoxometalates (POMs) as modulators. The local structure of the MOF nanotubes is investigated combining XANES and EXAFS studies. These nanotubes show both an excellent catalytic performance in the detoxification of sulfur compounds in O2 atmosphere and a remarkable cycling stability as the anode material for lithium‐ion batteries.