Shunt‐Blocking Layers for Semitransparent Perovskite Solar Cells. Issue 10 (22nd February 2016)

• Record Type: Journal Article
• Authors: Hörantner, Maximilian T.; Nayak, Pabitra K.; Mukhopadhyay, Sabyasachi; Wojciechowski, Konrad; Beck, Clara; McMeekin, David; Kamino, Brett; Eperon, Giles E.; Snaith, Henry J.
• Is Part Of: Advanced materials interfaces. Volume 3:Issue 10(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-02-22
• Subjects: perovskites -- semitransparency -- shunt‐blocking -- siloxane -- solar cells; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.201500837
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract : Perovskite solar cells have shown phenomenal progress and have great potential to be manufactured as low‐cost large area modules. However, perovskite films often suffer from pinholes and the resulting contact between hole‐ and electron transporting layers provides lower resistance (shunt) pathways, leading to decreased open‐circuit voltage and fill factor. This problem is even more severe in large area cells and especially in the case of neutral color semitransparent cells, where a large absorber‐free area is required to provide the desired transparency. Herein, a simple, inexpensive, and scalable wet chemical method is presented to block these "shunting paths" via deposition of transparent, insulating molecular layers, which preferentially bind to the uncovered surface of the electron collecting oxide, without hindering charge extraction from the perovskite to the charge collection layers. It is shown that this method improves the performance in semitransparent cells, where the enhancement in open‐circuit voltage is up to 30% without negatively impacting the photocurrent. Using this method, we achieved an efficiency of 6.1% for a neutral color semitransparent perovskite cell with 38% average visible transmittance. This simple shunt blocking technique has applications in improving the yield as well as efficiency of large area perovskite solar cells and light emitting devices. Abstract : Silane based, electrically insulated molecular layers are utilized that attach preferentially in the pin‐hole forming regions without hindering the charge transport in the active areas. Using a Ni microgrid‐based transparent top electrode, 6.1% PCE with 38% average visible transparency is demonstrated for a neutral color semitransparent perovskite solar cell.