Identifying and quantifying amorphous and crystalline content in complex powdered samples: application to archaeological carbon blacks. Issue 2 (24th March 2016)

• Record Type: Journal Article
• Authors: Cersoy, Sophie; Martinetto, Pauline; Bordet, Pierre; Hodeau, Jean Louis; Van Elslande, Elsa; Walter, Philippe
• Is Part Of: Journal of applied crystallography. Volume 49:Issue 2(2016)
• Page Start: 585
• Page End: 593
• Publication Date: 2016-03-24
• Subjects: powder X‐ray techniques -- phase identification and quantification -- archaeology; Crystallography -- Periodicals; 548.05
• DOI: 10.1107/S1600576716003551
• Languages: English
• ISSNs: 0021-8898

Abstract

Abstract : Five black carbon‐based archaeological powders from Pompeii are fully characterized by using a combination of nondestructive techniques. Characterizing these heterogeneous samples in this way provides a practical demonstration of a methodology available to be used for the identification, quantification and mapping of the crystalline and amorphous phases coexisting in a single sample. Abstract : Carbon black materials have been frequently used from prehistory as pigments for drawings and paintings and also as dyes, inks and cosmetics, since they are easy to make by burning organic matter. However, the carbonaceous phases they form are often ill‐ordered and not easy to characterize. Five carbon black Roman micro samples found in vessels in houses in Pompeii were studied. These precious powders correspond to mixed phase samples that contain both crystalline and ill‐ordered components. Here, a methodological approach that accomplishes the identification, quantification and mapping of the different phases in these heterogeneous samples using synchrotron‐based techniques is proposed. The results were compared with those from scanning electron microscopy. Information about the nature of the mixtures and the origin of carbon black pigments is obtained. The use of charred vegetable materials is concluded, independently of the shape and the nature of the container.