Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na‐Ion Charge Storage. Issue 9 (8th February 2016)

• Record Type: Journal Article
• Authors: Cook, John B.; Kim, Hyung‐Seok; Yan, Yan; Ko, Jesse S.; Robbennolt, Shauna; Dunn, Bruce; Tolbert, Sarah H.
• Is Part Of: Advanced energy materials. Volume 6:Issue 9(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-02-08
• Subjects: electrochemical‐energy storage -- pseudocapacitance -- lithium‐ion batteries -- MoS2 -- sodium‐ion batteries; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201501937
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four‐electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g −1 for Li‐ions and 118 mAh g −1 for Na‐ions at 1 mV s −1 . Utilizing synchrotron grazing incidence X‐ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso‐oriented crystal structure. When Li‐ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g −1 . Moreover, the nanoscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism. Abstract : Mesoporous MoS2 is synthesized via thermal sulfurization of block copolymer templated mesoporous MoO2 . These nanoporous films show high levels of pseudocapcitance using both Li + and Na + . When cycled with Li +, the material exhibits a reversible charge storage capacity of 140 mA h g −1 in only 20 s, and can be cycled more than 10 000 times.