An approach for the synthesis of nakamuric acid. Issue 22 (3rd June 2015)
- Record Type:
- Journal Article
- Title:
- An approach for the synthesis of nakamuric acid. Issue 22 (3rd June 2015)
- Main Title:
- An approach for the synthesis of nakamuric acid
- Authors:
- Wang, Xiaolei
Chen, Chuo - Abstract:
- Abstract: The biosynthesis of dimeric pyrrole–imidazole alkaloids is likely mediated by enzyme-catalyzed reversible single-electron transfer (SET) cycloaddition. We now show that Ir(ppy)3 can promote SET-mediated formal [2+2] and [4+2] cycloaddition reactions of pyrrole–imidazole alkaloids-related substrates under photolytic conditions. This biomimetic approach is useful for the construction of the core skeleton of nakamuric acid and sceptrin. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 71:Issue 22(2015)
- Journal:
- Tetrahedron
- Issue:
- Volume 71:Issue 22(2015)
- Issue Display:
- Volume 71, Issue 22 (2015)
- Year:
- 2015
- Volume:
- 71
- Issue:
- 22
- Issue Sort Value:
- 2015-0071-0022-0000
- Page Start:
- 3690
- Page End:
- 3693
- Publication Date:
- 2015-06-03
- Subjects:
- Single-electron transfer -- Radical -- Cyclization -- Imidazole -- Pyrrole
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2014.10.027 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1011.xml