1, 2, 3-Triazole amine as directing group in promoting catalytic oxidative C–H olefination under aerobic conditions. Issue 22 (2nd June 2016)
- Record Type:
- Journal Article
- Title:
- 1, 2, 3-Triazole amine as directing group in promoting catalytic oxidative C–H olefination under aerobic conditions. Issue 22 (2nd June 2016)
- Main Title:
- 1, 2, 3-Triazole amine as directing group in promoting catalytic oxidative C–H olefination under aerobic conditions
- Authors:
- Ye, Xiaohan
Zhang, Yanwei
He, Ying
Shi, Xiaodong - Abstract:
- Abstract: A practical ortho C–H olefination of phenyl acetic acid derivatives was achieved with a 1, 2, 3-triazole auxiliary directing group. Good to excellent yields were achieved with O2 as terminal oxidant. Other bidentate directing groups, such as 8-aminoquinoline, gave poor reactivity under this aerobic condition, highlighting the unique reactivity of triazole in promoting C–H activation. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 22(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 22(2016)
- Issue Display:
- Volume 72, Issue 22 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 22
- Issue Sort Value:
- 2016-0072-0022-0000
- Page Start:
- 2756
- Page End:
- 2762
- Publication Date:
- 2016-06-02
- Subjects:
- C–H activation -- 1, 2, 3-Triazole -- Oxidative heck -- Aerobic olefination -- Directing group
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.02.013 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 861.xml