Acid-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide: trapping alkenyl radicals by TEMPO. Issue 22 (2nd June 2016)
- Record Type:
- Journal Article
- Title:
- Acid-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide: trapping alkenyl radicals by TEMPO. Issue 22 (2nd June 2016)
- Main Title:
- Acid-catalyzed C–O coupling of styrenes with N-hydroxyphthalimide: trapping alkenyl radicals by TEMPO
- Authors:
- Xia, Xiao-Feng
Zhu, Su-Li
Niu, Yan-Ning
Zhang, Danting
Liu, Xiang
Wang, Haijun - Abstract:
- Abstract: A mild metal-free acid-catalyzed 1, 2-dihydroxylaminations of alkenes with N -hydroxyphthalimide and 2, 2, 6, 6-tetramethylpiperidine N -oxyl (TEMPO) has been demonstrated under air conditions to furnish the dioxygenated products in good to excellent yields. The dioxygenated product can be easily transformed into ketone derivative using 3-chloroperbenzoic acid ( m -CPBA) as the oxidant in a high yield. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 22(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 22(2016)
- Issue Display:
- Volume 72, Issue 22 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 22
- Issue Sort Value:
- 2016-0072-0022-0000
- Page Start:
- 3068
- Page End:
- 3072
- Publication Date:
- 2016-06-02
- Subjects:
- Acid-catalyzed -- C–O coupling -- N-hydroxyphthalimide -- TEMPO -- 1, 2-Dihydroxylaminations
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.04.028 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 861.xml