Shuttling as a Strategy to Control the Regiochemistry of Bis‐Additions on Fullerene Derivatives. Issue 12 (28th January 2016)

• Record Type: Journal Article
• Authors: Carini, Marco; Da Ros, Tatiana; Prato, Maurizio; Mateo‐Alonso, Aurelio
• Is Part Of: Chemphyschem. Volume 17:Issue 12(2016)
• Page Start: 1823
• Page End: 1828
• Publication Date: 2016-01-28
• Subjects: bis-adducts -- cycloaddition -- fullerenes -- rotaxanes -- selectivity; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201501174
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: The reactivity of a fullerene‐stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis‐adducts. Abstract : The reactivity of a fullerene‐stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere allosterically influences the second cycloaddition reaction, giving rise to a selected mixture of bis‐adducts.