ChemInform Abstract: Palladium‐Catalyzed [2 + 1] Cycloadditions Affording Vinylidenecyclopropanes as Precursors of 7‐Membered Carbocycles. Issue 27 (16th June 2016)

• Record Type: Journal Article
• Authors: Lepronier, Aymeric; Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Buono, Gerard; Clavier, Herve
• Is Part Of: ChemInform. Volume 47:Issue 27(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-06-16
• Subjects: bridged compounds (heterocyclic compounds) -- cyclopropanation reactions -- cycloaddition reactions -- catalysis, phase‐transfer catalysis -- ring opening reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201627120
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Palladium(II) acetate in association with secondary phosphine oxides provides an efficient catalytic system for [2+1] cycloadditions starting from oxanorbornene derivatives and tertiary propargyl esters giving rise to vinylidenecyclopropanes.