ChemInform Abstract: A Highly Regio‐ and Stereoselective Selenoxide Elimination of 1, 2‐Bis[4‐(trimethylsilyl)phenylseleno]alkanes to Give (E)‐Alkenyl Selenoxides and Its Mechanistic Study. Issue 26 (June 2016)

• Record Type: Journal Article
• Authors: Tarao, Asami; Niki, Aya; Komagawa, Shinsuke; Arimitsu, Kenji; Uchimoto, Hitomi; Kawasaki, Ikuo; Yamaguchi, Kentaro; Nishide, Kiyoharu
• Is Part Of: ChemInform. Volume 47:Issue 26(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-06
• Subjects: organo‐selenium compounds -- oxidation, dehydrogenation -- elimination reactions -- e/z‐selectivity (incl. e/z‐isomerism); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201626208
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Oxidation of organo‐selenium compounds (I) with MCPBA generates bisselenoxide intermediates which undergo elimination to give products (II) with high regio‐ and E/Z‐selectivity.