ChemInform Abstract: Zinc‐Catalyzed Enantioselective Electrophilic Amination of β‐Ketocarbonyl Compounds with Axially Chiral Phenanthroline Ligands. Issue 26 (June 2016)

• Record Type: Journal Article
• Authors: Naganawa, Yuki; Komatsu, Hiroyuki; Nishiyama, Hisao
• Is Part Of: ChemInform. Volume 47:Issue 26(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-06
• Subjects: aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- catalysis, phase‐transfer catalysis -- amination, N‐alkylation, N‐arylation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201626082
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Zinc‐catalyzed asymmetric α‐amination of various cyclic β‐ketocarbonyl compounds using azodicarboxylate (II) as the electrophilic nitrogen source is described.