Inside Cover: Electrocatalytic and Solar‐Driven CO2 Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO2 (Angew. Chem. Int. Ed. 26/2016). Issue 26 (4th May 2016)

• Record Type: Journal Article
• Authors: Rosser, Timothy E.; Windle, Christopher D.; Reisner, Erwin
• Is Part Of: Angewandte Chemie international edition. Volume 55:Issue 26(2016)
• Page Start: 7268
• Page End: 7268
• Publication Date: 2016-05-04
• Subjects: carbon dioxide -- electrocatalysis -- hybrid materials -- manganese -- reduction; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201603979
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : One small step for Mn A manganese catalyst immobilized on TiO2 gave a new benchmark turnover number as described by E. Reisner and co‐workers in their Communication onpage 7388 ff. The heterogenized catalyst operates at a low overpotential, which is the result of dimerization on the electrode surface. The molecular hybrid cathode was used in a photoelectrochemical cell enabling solar‐driven CO production by a photo‐unstable Mn catalyst for the first time.