ChemInform Abstract: Sequential 1, 4‐/1, 2‐Addition of Lithium(trimethylsilyl)diazomethane onto Cyclic Enones to Induce C—C Fragmentation and N—Li Insertion. Issue 25 (June 2016)

• Record Type: Journal Article
• Authors: O'Connor, Matthew J.; Sun, Chunrui; Guan, Xinyu; Sabbasani, Venkata R.; Lee, Daesung
• Is Part Of: ChemInform. Volume 47:Issue 25(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-06
• Subjects: reactions of organo‐metal compounds -- insertion reactions -- ring opening reactions -- ring closure reactions, annulation reactions -- pyrazole derivatives -- diazepine derivatives; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201625050
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Cyclic α, β‐unsaturated ketones undergo double additions with lithium(trimethylsilyl)diazomethane, effectively generating various molecular frameworks with complexity and diversity.