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ChemInform Abstract: Rhodium(II)‐Catalyzed Regioselective Carbenoid Insertion Reaction of Simple Indoles with N‐Sulfonyltriazoles: A Rapid Access to Tryptamine Vinylogues. Issue 23 (May 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Rhodium(II)‐Catalyzed Regioselective Carbenoid Insertion Reaction of Simple Indoles with N‐Sulfonyltriazoles: A Rapid Access to Tryptamine Vinylogues. Issue 23 (May 2016)
Main Title:
ChemInform Abstract: Rhodium(II)‐Catalyzed Regioselective Carbenoid Insertion Reaction of Simple Indoles with N‐Sulfonyltriazoles: A Rapid Access to Tryptamine Vinylogues.
Abstract: The rhodium‐catalyzed nitrogen extrusion from triazoles gives reactive rhodium(II) aza‐vinylcarbenes, which react with indoles to form predominantly Z‐isomers of tryptamine vinylogues.