Influence of Physicochemical Parameters of Organic Solutes on the Retention and Flux in a Nanofiltration Process. Issue 6 (18th February 2016)

• Record Type: Journal Article
• Authors: Hidalgo, Asunción M.; Gómez, María; Murcia, María D.; Gómez, Elisa; León, Gerardo; Cascales, Elisa
• Is Part Of: Chemical engineering & technology. Volume 39:Issue 6(2016:Jun.)
• Page Start: 1177
• Page End: 1184
• Publication Date: 2016-02-18
• Subjects: Membrane processes -- Nanofiltration -- NF‐97 membrane -- Organic compounds -- Physicochemical parameters; Chemical engineering -- Periodicals; Chemical processes -- Periodicals; 660.05
• DOI: 10.1002/ceat.201500254
• Languages: English
• ISSNs: 0930-7516

Abstract

Abstract: A comparative study of several organic compounds (atrazine, aniline and phenol, and their derivatives, 4‐chlorophenol, 4‐nitrophenol and 4‐nitroaniline) and their removal from aqueous solutions by nanofiltration using an NF‐97 polyamide membrane is presented. The aim was to ascertain any correlation between the physicochemical parameters of the different compounds and the characteristic parameters of the nanofiltration system (permeate flux and rejection coefficient), in order to understand the behavior of the nanofiltration membrane separation processes and any relevant variables. In a previous work, the rejection coefficients and permeate flux values for phenol, 4‐chlorophenol, aniline, and atrazine were obtained. These values were used together with the new ones presented for 4‐nitroaniline and 4‐nitrophenol. Abstract : The removal of atrazine, aniline, phenol, 4‐chlorophenol, 4‐nitrophenol, and 4‐nitroaniline with the NF‐97 polyamide nanofiltration membrane was studied in a flat‐membrane test module. Factors that affect the retention and flux of these molecules were identified using a multivariate statistical treatment.